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Adsorption and reactions of CH2Br2 on TiO2: Effects of H2O and O2
The adsorption, thermo- and photo-reactions of CH2Br2 on powdered TiO2 as well as the effects of H2O and/or O2 have been studied by Fourier-transform infrared spectroscopy. CH2Br2 is adsorbed molecularly on the surface at 35∘C, interacting with the surface OH groups. It is completely desorbed or…