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Chemical Reviews
Scopus
ISSN 0009-2665 · American Chemical Society · 244 artikel di indeks
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Artikel Jurnal
Selectivity in Chemiresistive Gas Sensors: Strategies and Challenges
The demand for highly functional chemical gas sensors has surged due to the increasing awareness of human health to monitor metabolic disorders or noncommunicable diseases, safety measures against harmful greenhouse and/or explosive gases, and determination of food freshness. Over the years of…
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Proton Exchange Membrane (PEM) Water Electrolysis: Cell-Level Considerations for Gigawatt-Scale Deployment
Hydrogen produced with no greenhouse gas emissions is termed "green hydrogen" and will be essential to reaching decarbonization targets set forth by nearly every country as per the Paris Agreement. Proton exchange membrane water electrolyzers (PEMWEs) are expected to contribute substantially to the…
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Artikel Jurnal
Comprehensive Review on the Structural Diversity and Versatility of Multi-Resonance Fluorescence Emitters: Advance, Challenges, and Prospects toward OLEDs
Fluorescence emitters with a multiple-resonant (MR) effect have become a research hotspot. These MR emitters mainly consist of polycyclic aromatic hydrocarbons with boron/nitrogen, nitrogen/carbonyl, and indolocarbazole frameworks. The staggered arrangement of the highest occupied molecular orbital…
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Precious Metal Free Hydrogen Evolution Catalyst Design and Application
The quest to identify precious metal free hydrogen evolution reaction catalysts has received unprecedented attention in the past decade. In this Review, we focus our attention to recent developments in precious metal free hydrogen evolution reactions in acidic and alkaline electrolyte owing to…
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Artikel Jurnal
Theranostic Fluorescent Probes
The ability to gain spatiotemporal information, and in some cases achieve spatiotemporal control, in the context of drug delivery makes theranostic fluorescent probes an attractive and intensely investigated research topic. This interest is reflected in the steep rise in publications on the topic…
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The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation
2017, 1605444), we here comprehensively document subsequent advances made in TADF materials design and their uses from 2017-2022. Correlations highlighted between structure and properties as well as detailed comparisons and analyses should assist future TADF materials development. The necessarily…
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Depolymerization within a Circular Plastics System
The societal importance of plastics contrasts with the carelessness with which they are disposed. Their superlative properties lead to economic and environmental efficiency, but the linearity of plastics puts the climate, human health, and global ecosystems at risk. Recycling is fundamental to…
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Introduction to Green Hydrogen
Green hydrogen, produced through water electrolysis powered by renewable energy, is an essential component of future global energy systems.Green hydrogen is produced through water electrolysis powered by renewable energy sources, such as wind, solar, or hydropower, or possibly nuclear energy…
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Artikel Jurnal
Hydrogen Embrittlement as a Conspicuous Material Challenge─Comprehensive Review and Future Directions
Hydrogen is considered a clean and efficient energy carrier crucial for shaping the net-zero future. Large-scale production, transportation, storage, and use of green hydrogen are expected to be undertaken in the coming decades. As the smallest element in the universe, however, hydrogen can adsorb…
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Artikel Jurnal
Self-Driving Laboratories for Chemistry and Materials Science
Self-driving laboratories (SDLs) promise an accelerated application of the scientific method. Through the automation of experimental workflows, along with autonomous experimental planning, SDLs hold the potential to greatly accelerate research in chemistry and materials discovery. This review…
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Chiral Induced Spin Selectivity
Since the initial landmark study on the chiral induced spin selectivity (CISS) effect in 1999, considerable experimental and theoretical efforts have been made to understand the physical underpinnings and mechanistic features of this interesting phenomenon. As first formulated, the CISS effect…
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Artikel Jurnal
Fluorescent Probes for Disease Diagnosis
. In this review, we describe current fluorescent probes designed for the detection and quantification of key bioactive molecules associated with common diseases, such as organ damage, inflammation, cancers, cardiovascular diseases, and brain disorders. We emphasize the strategies behind the design…
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Polymeric Nanoparticles for Drug Delivery
The recent emergence of nanomedicine has revolutionized the therapeutic landscape and necessitated the creation of more sophisticated drug delivery systems. Polymeric nanoparticles sit at the forefront of numerous promising drug delivery designs, due to their unmatched control over physiochemical…
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Separators and Membranes for Advanced Alkaline Water Electrolysis
Traditionally, alkaline water electrolysis (AWE) uses diaphragms to separate anode and cathode and is operated with 5-7 M KOH feed solutions. The ban of asbestos diaphragms led to the development of polymeric diaphragms, which are now the state of the art material. A promising alternative is the…
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Single Atom Catalysts Based on Earth-Abundant Metals for Energy-Related Applications
Anthropogenic activities related to population growth, economic development, technological advances, and changes in lifestyle and climate patterns result in a continuous increase in energy consumption. At the same time, the rare metal elements frequently deployed as catalysts in energy related…
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Plasmon-Induced Hot Electrons in Nanostructured Materials: Generation, Collection, and Application to Photochemistry
Plasmon refers to the coherent oscillation of all conduction-band electrons in a nanostructure made of a metal or a heavily doped semiconductor. Upon excitation, the plasmon can decay through different channels, including nonradiative Landau damping for the generation of plasmon-induced energetic…
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Carbon Nanomaterial Fluorescent Probes and Their Biological Applications
Fluorescent carbon nanomaterials have broadly useful chemical and photophysical attributes that are conducive to applications in biology. In this review, we focus on materials whose photophysics allow for the use of these materials in biomedical and environmental applications, with emphasis on…
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Artikel Jurnal
Catalytic Upcycling of Polyolefins
The large production volumes of commodity polyolefins (specifically, polyethylene, polypropylene, polystyrene, and poly(vinyl chloride)), in conjunction with their low unit values and multitude of short-term uses, have resulted in a significant and pressing waste management challenge. Only a small…
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Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis
)-C(sp) bond formation. Additional chapters include alkene difunctionalization, alkyne difunctionalization, and formation of carbon-heteroatom bonds. Each chapter is generally organized with an initial summary of mechanisms followed by detailed figures and notes on methodological developments and…
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Artikel Jurnal
Visible Light-Induced Reactions of Diazo Compounds and Their Precursors
In recent years, visible light-induced reactions of diazo compounds have attracted increasing attention in organic synthesis, leading to improvement of existing reactions, as well as to the discovery of unprecedented transformations. Thus, photochemical or photocatalytic generation of both carbenes…